If you actually want to understand skolemization, I recommend at first you read the first section of this lecture:
Lecture 9: Analytic Tableaux vs. Refinement logic. In: CS 4860: Applied Logic (Fall 2012), Cornell University: Computer Science.
Now, note that Fφ is a shorthand for I(φ)=false, where I is an interpretation. An interpretation is simply a row of the truth table: each variable gets a truth value. One does the following:
(1) (|= φ) ⇔ ∀I(I(φ)=true) ⇔ ¬∃I(I(φ)=false)
and shows by analytic tableaux method that I(φ)=false is not satisfiable. Note that (1) is a statement in metalanguage, i.e. the quantifiers in (1) do not belong to object language. By ∀I and ∃I you basically express a quantification over all rows of the truth table.
By the way: try to compare analytic tableaux complexity with brute force truth table evaluation.
Next, the question arises, whether it is possible to transfer this method from propositional calculus to first-order predicate calculus. It must be said that predicate calculus is more complex:
- you need to introduce the notion of free/bound variables,
- interpretations can also assign functions to function symbols,
- the number of interpretations may be infinite.
Some analytic tableaux examples are stated in Wikipedia: First-order logic tableau.
By skolemization you obtain an equisatisfiable formula with existential quantifiers removed. I believe an existential quantifier would mean a tableaux node with an infinite number of edges, and by skolemization you shrink them together to a single edge. The formula will not be equivalent, but this is not a problem, as we only need to show satisfiability/unsatisfiability.