I don't think that's going to happen, because it's a pretty drastic change to what it means to use a type, and it would make a whole bunch of plausible proc macros no longer sound.
If someone wants a niche in a type, I think it's better to represent that by adding an actual field.
Once can make a
#[repr(u8)] enum ZeroByte { Zero = 0 }
and add a field of that type, and the niche optimizations will start to happen.
Then by it being a real field, the "this byte needs to be zero" property is a normal consequence of an ordinary validity invariant.
(And obligatory mention of Pre-pre-RFC: syntactic sugar for `Default::default()` - #75 by ekuber that would let such a field be defaulted and thus less annoying to use.)